It was narrated that Anas said:

"The Messenger of Allah ﷺ entered upon us and the only people present were myself, my mother, the orphan and Umm Harh, my maternal aunt. He said: 'Stand up and I will lead you in prayer.' It was not the time for a (prescribed) prayer. And he led us in prayer."

أَخْبَرَنَا سُوَيْدُ بْنُ نَصْرٍ، قَالَ أَنْبَأَنَا عَبْدُ اللَّهِ بْنُ الْمُبَارَكِ، عَنْ سُلَيْمَانَ بْنِ الْمُغِيرَةِ، عَنْ ثَابِتٍ، عَنْ أَنَسٍ، قَالَ دَخَلَ عَلَيْنَا رَسُولُ اللَّهِ ﷺ وَمَا هُوَ إِلاَّ أَنَا وَأُمِّي وَالْيَتِيمُ وَأُمُّ حَرَامٍ خَالَتِي فَقَالَ " قُومُوا فَلأُصَلِّيَ بِكُمْ " . قَالَ فِي غَيْرِ وَقْتِ صَلاَةٍ - قَالَ - فَصَلَّى بِنَا .